Impossible for me to qualify because the choices are mindboggling!
Aside from Eno, I would say my favorite single ambient release is the three CD set
A Storm of Drones (Sombient-Asphodel, 1997). There's sooo much great stuff packed into this collection:
Steve Roach
Robert Rich
Robert Normandeau
Francis Dhomont
Alan Lamb
Maryanne Amacher
Jeff Greinke
Stuart Dempster
...and many many more.
While
A Storm of Drones was marketed as
ambient, monst of the artists weren't strictly ambient. A lot of them were electroacoustic artists you can find on empreintes DIGITALes of Montreal (
http://www.electrocd.com).
My favorite label for Ambient music is Hypnos (
http://www.hypnos.com), which is run by M. Griffin, an Ambient artist himself.
An absolutely superb Ambient CD I just pulled out of my collection today is Vidna Obmana & Willem Tanke:
Variations for Organ, Keyboards and Processors.